Electrochemically induced synthesis of beta-lactams, by cyclization (via C3-C4 bond formation) of haloamides (XCHRCONRCHRR4)-C-1-C-2-R-3 (X: Br, Cl), has been achieved in suitable solvent-supporting electrolyte solutions previously electrolyzed under galvanostatic control. The yields and the stereochemistry of the process are affected by the nature of substituents R-1-R-4 and of solvent-supporting electrolyte solutions and by the electrolysis conditions

An electrochemical alternative strategy to the synthesis of beta-lactams - Part 2. C3-C4 bond formation

ROSSI, LEUCIO;
2006

Abstract

Electrochemically induced synthesis of beta-lactams, by cyclization (via C3-C4 bond formation) of haloamides (XCHRCONRCHRR4)-C-1-C-2-R-3 (X: Br, Cl), has been achieved in suitable solvent-supporting electrolyte solutions previously electrolyzed under galvanostatic control. The yields and the stereochemistry of the process are affected by the nature of substituents R-1-R-4 and of solvent-supporting electrolyte solutions and by the electrolysis conditions
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11697/10256
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