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EnglishElectrochemically induced synthesis of beta-lactams, by cyclization (via C3-C4 bond formation) of haloamides (XCHRCONRCHRR4)-C-1-C-2-R-3 (X: Br, Cl), has been achieved in suitable solvent-supporting electrolyte solutions previously electrolyzed under galvanostatic control. The yields and the stereochemistry of the process are affected by the nature of substituents R-1-R-4 and of solvent-supporting electrolyte solutions and by the electrolysis conditions
| Titolo: | An electrochemical alternative strategy to the synthesis of beta-lactams - Part 2. C3-C4 bond formation |
| Autori: | |
| Data di pubblicazione: | 2006 |
| Rivista: | |
| Abstract: | Electrochemically induced synthesis of beta-lactams, by cyclization (via C3-C4 bond formation) of haloamides (XCHRCONRCHRR4)-C-1-C-2-R-3 (X: Br, Cl), has been achieved in suitable solvent-supporting electrolyte solutions previously electrolyzed under galvanostatic control. The yields and the stereochemistry of the process are affected by the nature of substituents R-1-R-4 and of solvent-supporting electrolyte solutions and by the electrolysis conditions |
| Handle: | http://hdl.handle.net/11697/10256 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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