The palladium-catalyzed cyclization of 5-alkyl-5-[2-(o-iodophenylcarbamoyl)vinyl] derivatives of Meldrum's acid produces 3-alkylidene oxindoles containing the Meldrum's acid moiety. These compunds can be useful synthetic intermediates. An application to the synthesis of functionalized carbazoles through the intermediacy of 3,5,6-trisubstituted 2H-pyran-2-ones is reported.
5-Alkyl-5-[2-(o-iodophenylcarbamoyl)vinyl] Derivatives of Meldrum's Acid as Substrates for the Intramolecular Heck Reaction: Application to the Synthesis of Carbazoles
ARCADI A;MARINELLI, Fabio;
1993-01-01
Abstract
The palladium-catalyzed cyclization of 5-alkyl-5-[2-(o-iodophenylcarbamoyl)vinyl] derivatives of Meldrum's acid produces 3-alkylidene oxindoles containing the Meldrum's acid moiety. These compunds can be useful synthetic intermediates. An application to the synthesis of functionalized carbazoles through the intermediacy of 3,5,6-trisubstituted 2H-pyran-2-ones is reported.File in questo prodotto:
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