An aldol-reduction one-pot sequence allows syn-syn polyketide fragments such as 7 to be obtained enantio and diastereoselectively. Enol Diisopinocampheylborinate is able to influence both the aldol and the subsequent reduction with NaBH4, via a chelate chair like intermediate.
Titolo: | Boron Mediated One-Pot Aldol-reduction Sequence: Enantio and Diastereoselective Synthesis of Typical Polyketide Fragments |
Autori: | |
Data di pubblicazione: | 1994 |
Rivista: | |
Abstract: | An aldol-reduction one-pot sequence allows syn-syn polyketide fragments such as 7 to be obtained enantio and diastereoselectively. Enol Diisopinocampheylborinate is able to influence both the aldol and the subsequent reduction with NaBH4, via a chelate chair like intermediate. |
Handle: | http://hdl.handle.net/11697/12030 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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