Switch it on! The activity of an organocatalytic group incorporated within a rotaxane architecture can be controlled by switching the position of the macrocycle. The system was used to mediate the progress of the Michael addition of an aliphatic thiol to trans-cinnamaldehyde. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A rotaxane-based switchable organocatalyst
Carlone, Armando;
2012-01-01
Abstract
Switch it on! The activity of an organocatalytic group incorporated within a rotaxane architecture can be controlled by switching the position of the macrocycle. The system was used to mediate the progress of the Michael addition of an aliphatic thiol to trans-cinnamaldehyde. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.File in questo prodotto:
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