A 2D FT double-resonance imaging method for nuclei having a low gyromagnetic ratio is presented. The method is based on the twin-SEDOR pulse sequence that allows one to detect the signal only from the protons coupled to the rare nuclei by indirect interaction. The method was tested on boron-10-enriched Na2B12H11SH (BSH), in which the boron-10 played the role of the rare nucleus. The indirect imaging of the molecules containing boron-10 is obtained with a signal-to-noise ratio given by the coupled protons and with an effective suppression of the solvent signal. Â© 1995 Academic Press, Inc.
|Titolo:||Twin-SEDOR Spin-Warp Imaging of Low Gyromagnetic Ratio Nuclei|
|Data di pubblicazione:||1995|
|Appare nelle tipologie:||1.1 Articolo in rivista|