A convenient and efficient C–H insertion reaction of environment friendly H2O2 into representative hydrocarbon derivatives by homogeneous methyltrioxorhenium (MTO), heterogeneous poly(4-vinylpyridine)/methyltrioxorhenium (PVP/MTO) and microencapsulated polystyrene/methyltrioxorhenium (PS/MTO) systems in ionic liquids, is described. In some cases a higher activity was observed if compared with the same reaction in molecular solvents. The heterogeneous catalysts are stable systems under the reaction conditions and can be recycled for more transformations.

Highly Efficient C-H Insertion Reactions of Hydrogen Peroxide Catalyzed by Homogeneous and Heterogeneous Methyltrioxorhenium Systems in Ionic Liquids

CRUCIANELLI, MARCELLO;DE ANGELIS, Francesco;
2005

Abstract

A convenient and efficient C–H insertion reaction of environment friendly H2O2 into representative hydrocarbon derivatives by homogeneous methyltrioxorhenium (MTO), heterogeneous poly(4-vinylpyridine)/methyltrioxorhenium (PVP/MTO) and microencapsulated polystyrene/methyltrioxorhenium (PS/MTO) systems in ionic liquids, is described. In some cases a higher activity was observed if compared with the same reaction in molecular solvents. The heterogeneous catalysts are stable systems under the reaction conditions and can be recycled for more transformations.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11697/12587
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 59
  • ???jsp.display-item.citation.isi??? 54
social impact