The reaction of acetylenic amines 1 with electrochemically generated tetraethylammonium carbonate (TEAC) or chemically generated tetraethylammonium hydrogen carbonate (TEAHC) is reported. Unsubstituted or substituted 5-methylene-1,3-oxazolidin-2-ones 2 are obtained in moderate to very high yields according to the reaction conditions adopted and to the nature of the substrate.
Titolo: | The reaction of acetylenic amines with tetraethylammonium carbonate and hydrogen carbonate: synthesis of 5-Methylene-1,3-oxazolidin-2-ones |
Autori: | |
Data di pubblicazione: | 2005 |
Rivista: | |
Abstract: | The reaction of acetylenic amines 1 with electrochemically generated tetraethylammonium carbonate (TEAC) or chemically generated tetraethylammonium hydrogen carbonate (TEAHC) is reported. Unsubstituted or substituted 5-methylene-1,3-oxazolidin-2-ones 2 are obtained in moderate to very high yields according to the reaction conditions adopted and to the nature of the substrate. |
Handle: | http://hdl.handle.net/11697/12728 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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