The sequential rhodium-catalyzed addition/lactonization reaction of organoboron derivatives to alkyl 4-hydroxy-2-alkynoates would constitute a novel methodology for the synthesis of 4-aryl/heteroaryl/ vinyl-2(5H)-furanones with an excellent control of the regio- and chemoselectivity. The role played by rhodium precatatyst, ligands, reaction medium, and the feature of organoboron derivatives has been explored
Sequential Rhodium-Catalyzed Stereo- and Regioselective Addition of Organoboron Derivatives to the Alkyl 4-Hydroxy-2-Alkynoates/Lactonization Reaction
MARINELLI, Fabio;ARCADI, Antonio
2007-01-01
Abstract
The sequential rhodium-catalyzed addition/lactonization reaction of organoboron derivatives to alkyl 4-hydroxy-2-alkynoates would constitute a novel methodology for the synthesis of 4-aryl/heteroaryl/ vinyl-2(5H)-furanones with an excellent control of the regio- and chemoselectivity. The role played by rhodium precatatyst, ligands, reaction medium, and the feature of organoboron derivatives has been exploredFile in questo prodotto:
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