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EnglishThe sequential rhodium-catalyzed addition/lactonization reaction of organoboron derivatives to alkyl 4-hydroxy-2-alkynoates would constitute a novel methodology for the synthesis of 4-aryl/heteroaryl/ vinyl-2(5H)-furanones with an excellent control of the regio- and chemoselectivity. The role played by rhodium precatatyst, ligands, reaction medium, and the feature of organoboron derivatives has been explored.
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http://hdl.handle.net/11697/13246| Titolo: | Sequential Rhodium-Catalyzed Stereo- and Regioselective Addition of Organoboron Derivatives to the Alkyl 4-Hydroxy-2-Alkynoates/Lactonization Reaction |
| Autori interni: | MARINELLI, Fabio |
| Data di pubblicazione: | 2007 |
| Rivista: | JOURNAL OF ORGANIC CHEMISTRY |
| Abstract: | The sequential rhodium-catalyzed addition/lactonization reaction of organoboron derivatives to alkyl 4-hydroxy-2-alkynoates would constitute a novel methodology for the synthesis of 4-aryl/heteroaryl/ vinyl-2(5H)-furanones with an excellent control of the regio- and chemoselectivity. The role played by rhodium precatatyst, ligands, reaction medium, and the feature of organoboron derivatives has been explored. |
| Handle: | http://hdl.handle.net/11697/13246 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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