Abstract: Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of CH acid-containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.

Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte

LAURA PALOMBI
2006-01-01

Abstract

Abstract: Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of CH acid-containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/145712
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