Pacman bites selectively! Stable rhodium(III)-N-heterocyclic carbene-hydride complexes (Pacman-like catalysts) are highly active and selective catalysts for H/D exchange at the β position of aromatic α-olefins (see picture). The interplay between bulky N-heterocyclic carbene and quinolinate ligands determines the size of the steric window responsible for this selectivity. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts

Di Giuseppe A.;
2011

Abstract

Pacman bites selectively! Stable rhodium(III)-N-heterocyclic carbene-hydride complexes (Pacman-like catalysts) are highly active and selective catalysts for H/D exchange at the β position of aromatic α-olefins (see picture). The interplay between bulky N-heterocyclic carbene and quinolinate ligands determines the size of the steric window responsible for this selectivity. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
File in questo prodotto:
File Dimensione Formato  
5-Castarlenas-ACIE-2011-3938.pdf

non disponibili

Licenza: Creative commons
Dimensione 393.63 kB
Formato Adobe PDF
393.63 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/166398
Citazioni
  • ???jsp.display-item.citation.pmc??? 6
  • Scopus 68
  • ???jsp.display-item.citation.isi??? ND
social impact