The hydrothiolation of unsaturated carbon-carbon bonds is a practical and atom-economical approach for the incorporation of sulfur into organic frameworks. In recent years, we have witnessed the development of a range of transition-metal-based catalytic systems for the control of the regio- and stereoselectivity. In this Minireview we highlight the mechanistic background behind this transformation so as to help the design of more specific and active organometallic hydrothiolation catalysts. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
|Titolo:||The emergence of transition-metal-mediated hydrothiolation of unsaturated carbon-carbon bonds: A mechanistic outlook|
|Data di pubblicazione:||2013|
|Appare nelle tipologie:||1.1 Articolo in rivista|