The European research project CLARA (G.A. 817841) has studied pretreated residual biomasses for chemical looping gasification. This work investigated devolatilizations of wheat straw pellets (raw, torrefied, and torrefied-washed) at 700 °C, 800 °C, and 900 °C, performed in fluidized beds made of sand or three oxygen carriers (OCs): integral-average values (gas yield, H2/CO molar ratio, and carbon conversion) were calculated; instantaneous peaks of released syngas were evaluated by regression straight lines. For all biomasses and bed materials, the temperature increase (from 700 to 900 °C) was the dominant parameter, positively affecting all integral-average values. The OCs appeared more active at 900 °C. Biomass pretreatments improved the H2/CO molar ratio and decreased carbon conversion. SEM analyses showed that the purpose of washing (removal of low-melting elements) may be jeopardized by OCs’ composition.

Pretreated residual biomasses in fluidized beds for chemical looping Gasification: Experimental devolatilizations and characterization of ashes behavior

Di Giuliano A.;Gallucci K.
2022-01-01

Abstract

The European research project CLARA (G.A. 817841) has studied pretreated residual biomasses for chemical looping gasification. This work investigated devolatilizations of wheat straw pellets (raw, torrefied, and torrefied-washed) at 700 °C, 800 °C, and 900 °C, performed in fluidized beds made of sand or three oxygen carriers (OCs): integral-average values (gas yield, H2/CO molar ratio, and carbon conversion) were calculated; instantaneous peaks of released syngas were evaluated by regression straight lines. For all biomasses and bed materials, the temperature increase (from 700 to 900 °C) was the dominant parameter, positively affecting all integral-average values. The OCs appeared more active at 900 °C. Biomass pretreatments improved the H2/CO molar ratio and decreased carbon conversion. SEM analyses showed that the purpose of washing (removal of low-melting elements) may be jeopardized by OCs’ composition.
File in questo prodotto:
File Dimensione Formato  
Pretreated-residual-biomasses-in-fluidized-beds-for-chemical-looping-Gasification-Experimental-devolatilizations-and-characterization-of-ashes-behaviorBioresource-Technology.pdf

solo utenti autorizzati

Tipologia: Documento in Post-print
Licenza: Creative commons
Dimensione 9.22 MB
Formato Adobe PDF
9.22 MB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/175059
Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 9
  • ???jsp.display-item.citation.isi??? 9
social impact