The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.

Controlled monodefluorination and alkylation of C(sp3)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity

Andrea Di Giuseppe;
2022-01-01

Abstract

The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/195451
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