The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.
Controlled monodefluorination and alkylation of C(sp3)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity
Andrea Di Giuseppe;
2022-01-01
Abstract
The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.File in questo prodotto:
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