2,3-epoxy alcohols 1-tosylates are regio and chemoselectively opened to the corresponding (I, Br, Cl); the reduction of iodohydrins to the monoprotected diols and subsequent standard coupling of the tosyl group to a straightforward synthesis of optically active naturally occurring pheromones
Ring Opening of 2,3-Epoxy 1-Tosylates to Halohydrins and Subsequent Elaboration to Asymmetrical Alcohols
ROSSI, LEUCIO;
1994-01-01
Abstract
2,3-epoxy alcohols 1-tosylates are regio and chemoselectively opened to the corresponding (I, Br, Cl); the reduction of iodohydrins to the monoprotected diols and subsequent standard coupling of the tosyl group to a straightforward synthesis of optically active naturally occurring pheromonesFile in questo prodotto:
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