In this study, we explored the use of Deep Eutectic Solvents (DESs) as a green and sustainable alternative for the synthesis of Iron Oxide Nanoparticles (IONs). Six different binary mixtures of Hydrogen Bond Acceptors (HBAs) and Donors (HBDs) were prepared and thoroughly characterized to investigate how their components and physicochemical properties influence the structure, morphology, and magnetic properties of the resulting IONs. In addition, the role of DESs was assessed using ATR-MIR spectroscopy, providing insights into HBA-HBD interactions with iron precursors. The study highlights the critical role of DES constituents, particularly the interactions between HBAs and HBDs, in directing nanoparticle size, structure, and morphology. Indeed, our results demonstrate that the choice of DES significantly impacts the crystalline phase of iron oxide nanoparticles, yielding either magnetite (Fe₃O₄) or hematite (α-Fe₂O₃). These findings established a robust framework for leveraging DES in nanomaterial synthesis, paving the way for more environmentally friendly approaches in diverse industrial and scientific applications.

The Use of Deep Eutectic Solvents for the Synthesis of Iron Oxides Nanoparticles: A Driving Force for Materials Properties

Francesco Gabriele;Roberta Colaiezzi;Andrea Lazzarini
;
Franco D'Orazio;Valeria Daniele;Giuliana Taglieri;Nicoletta Spreti;Marcello Crucianelli
2025-01-01

Abstract

In this study, we explored the use of Deep Eutectic Solvents (DESs) as a green and sustainable alternative for the synthesis of Iron Oxide Nanoparticles (IONs). Six different binary mixtures of Hydrogen Bond Acceptors (HBAs) and Donors (HBDs) were prepared and thoroughly characterized to investigate how their components and physicochemical properties influence the structure, morphology, and magnetic properties of the resulting IONs. In addition, the role of DESs was assessed using ATR-MIR spectroscopy, providing insights into HBA-HBD interactions with iron precursors. The study highlights the critical role of DES constituents, particularly the interactions between HBAs and HBDs, in directing nanoparticle size, structure, and morphology. Indeed, our results demonstrate that the choice of DES significantly impacts the crystalline phase of iron oxide nanoparticles, yielding either magnetite (Fe₃O₄) or hematite (α-Fe₂O₃). These findings established a robust framework for leveraging DES in nanomaterial synthesis, paving the way for more environmentally friendly approaches in diverse industrial and scientific applications.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/261719
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