Epsilon-near-zero nonlinearity enhancement in the extreme ultraviolet

Materials with a vanishing dielectric constant provide an ideal platform for achieving plasmon-enhanced light-matter interactions and are widely employed in various cutting-edge nonlinear photonics applications. In this study, we present the first experimental demonstration of extreme ultraviolet (XUV) plasmon-enhanced self-driven spectral modification using a submicrometric foil of aluminium. This is achieved through the excitation of widely tunable Ferrell-Berreman epsilon-near-zero resonances with extremely low absorption. Our angle-dependent measurements of spectral modulation enhancement, supported by theoretical analysis, reveal efficient spectral modification at peak intensities as low as 380 GW/cm2, which we attribute to ultrafast heating and saturation effects. These findings mark a breakthrough in the enhancement of typically weak nonlinearities in the XUV regime through nonlinear plasmonics, potentially paving the way for unprecedented tools for the manipulation and control of XUV radiation.