The preparation and characterization of a solvent-switchable rotaxane that shuttles in the opposite direction to that expected are reported. The reverse shuttling is confirmed by NMR spectroscopy and can be monitored by cyclic voltammetry. The electrochemically generated anions on the fullerene moiety are stabilized by the closer proximity of the macrocycle.

Reverse Shuttling in a Fullerene-Stoppered Rotaxane

FIORAVANTI, GIULIA;
2006-01-01

Abstract

The preparation and characterization of a solvent-switchable rotaxane that shuttles in the opposite direction to that expected are reported. The reverse shuttling is confirmed by NMR spectroscopy and can be monitored by cyclic voltammetry. The electrochemically generated anions on the fullerene moiety are stabilized by the closer proximity of the macrocycle.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11697/3324
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