A new efficient gold(III) catalysed synthesis of beta-enaminones from 1,3-dicarbonyl compounds and ammonia/amines providing an attractive and environmental friendly alternative to the more vigorous reagents and drastic conditions of the existing methodologies is described; the catalysis of gold(III) is also extended to reaction of cyclic 1,3-dicarbonyls with O-, P- and S-nucleophiles.
Titolo: | Gold catalysis in the reaction of 1,3-dicarbonyls with nucleophiles |
Autori: | |
Data di pubblicazione: | 2003 |
Rivista: | |
Abstract: | A new efficient gold(III) catalysed synthesis of beta-enaminones from 1,3-dicarbonyl compounds and ammonia/amines providing an attractive and environmental friendly alternative to the more vigorous reagents and drastic conditions of the existing methodologies is described; the catalysis of gold(III) is also extended to reaction of cyclic 1,3-dicarbonyls with O-, P- and S-nucleophiles. |
Handle: | http://hdl.handle.net/11697/7250 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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